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KMID : 1059519900340030297
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Journal of the Korean Chemical Society
1990 Volume.34 No. 3 p.297 ~ p.303
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Kinetics and Mechanism of the Oxidation of n-Butylamine with Hydrogen Peroxide in the Presence of V(Ⅳ)
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Kim Chang-Su
Ju Keun-Hong
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Abstract
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VO2+-catalyzed oxidation of n-butylamine by hydrogen peroxide shows that the reaction is a first order in the concentration of n-butylamine, acid added, and VO2+ as catalyst, respectively. The reactions involve the initial formation of an imine intermediate, followed by hydrolysis to butyraldehyde and ammonia. It is suggested that the rate-determining step is a process dehydrogenation of n-butylammine.
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